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          PF-TD2PO1發(fā)光材料
          
						
          
							發(fā)布時間：2021-08-23     作者：zhn   分享到：
							
          
								
          
								
							
          
						
          
						
          
						
          PF-TD2PO1發(fā)光材料
          PF-TD2PO1結(jié)構(gòu)式如下：
          image.png
          The copolymer PF-TD2PO1 which contains 1 mol% PO unit shows a maximum luminous efficiency (LE max) of 3.07 cd A ?1 and 5.18 cd A ?1 based on single-layer and double-layer devices, respectively, with deep-blue Commission Internationale de L’E’clairage (CIE) coordinates of (0.15, 0.11).
          image.png
          文獻(xiàn)：
          A series of deep-blue light-emitting copolymers with an emission peak at 455 nm and narrow full width at half-maximum (FWHM) of about 40 nm were synthesized by incorporating a small amount of 10-(4-hexylphenyl)-10H-phenoxazine (PO) unit into the backbone of poly(9,9-dioctylfluorene). All the copolymers exhibit good thermal stability, high photoluminescent quantum yield and appropriate electrochemical energy levels. The copolymer PF-TD2PO1 which contains 1 mol% PO unit shows a maximum luminous efficiency (LEmax) of 3.07 cd A?1 and 5.18 cd A?1 based on single-layer and double-layer devices, respectively, with deep-blue Commission Internationale de L’E’clairage (CIE) coordinates of (0.15, 0.11). To improve the hole transport of the emissive layer, a hole transport molecule N-([1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazo-yl)-phenyl)-9H-fluorene-2-amine (BCFN) was blended into PF-TD2PO1. As a result, the best electroluminescence performance with a low turn-on voltage of 3.0 V, a superior LEmax of 6.20 cd A?1 (corresponding to a maximum external quantum efficiency of 6.22%), an unprecedented luminance of 44?685 cd m?2 and deep-blue CIE coordinates of (0.15, 0.11) were obtained from the blended PF-TD2PO1:BCFN light emitting device. It is particularly important that PF-TD2PO1:BCFN based devices exhibit very slow efficiency roll-off and a more than 14 times enhanced lifetime compared with the devices without BCFN. The results indicate the great potential of this class of copolymers for application in solution processed deep-blue light-emitting diodes with high efficiency and long lifetime.
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          溫馨提醒：僅供科研zhn2021.08.13
           
           

          
						
          
						
          
							
							
						
          
					
          
				
          
			
          
		
          
	
          

    







          
		
          
			
			
			
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